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Be sure to read manufacturers recommendation on the container, they often warn of conflicts with other finishes. Lacquers and enamels generally are incompatible, my old memory is hazy on this but you can apply them in a specific order. Enamel first, let dry completely and then lacquer over it I think it is. Anyway, the best way to find out is try shafts with different finishes and see what works for you.
I normally use MW Spar Ureathane on bows and arrows, good weather protection but it yellows slightly so might not give the results you seek over a white cap.
Like Larry, I use Duco on everything, fletching, rests, nocks. Have fun.